Counter-ion effects switch ligand binding from C-2 to C-5 in kinetic carbenes formed from an imidazolium salt and IrH5(PPh3)2
- 8 October 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2580-2581
- https://doi.org/10.1039/b207588c
Abstract
Changing the counter-anion in 2-pyridylmethyl imidazolium salts (Br, BF4, PF6, SbF6) causes their kinetic reaction products with IrH5(PPh3)2 to be switched from normal C-2 to abnormal C-5 binding.This publication has 17 references indexed in Scilit:
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