Template synthesis of polyiodide belt at a metal complex cation: structure of [([16]aneS4)M–I–M([16]aneS4)]3+[I5–]2i–(M = Pd, Pt) incorporating a symmetric linear M–I–M bridge ([16]aneS4= 1,5,9,13-tetrathiacyclohexadecane)
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 2207-2208
- https://doi.org/10.1039/cc9960002207
Abstract
Reaction of [M([16]aneS4)][PF6]2 with NBun 4I3 affords the binucleas species [([16]aneS4)M–I–M([16]aneS4)]3+(M = Pd, Pt) incorporating a highly unusual linear M–I–M moiety within a conformationally constrained environment: the counter anion, which can be regarded formally as two I5 – and One I– or alternatively as two I3 –, two I2 and one I–, forms a belt around the complex cation with the metal-bridging I– placed at its centre.Keywords
This publication has 28 references indexed in Scilit:
- Crown thioether chemistryPublished by Springer Nature ,2006
- The Catalytic Ring‐opening Cyclooligomerization (ROC) of Thietane by the Complexes M(CO) 5 L (M Cr and W; L = CO, thietane and 1,5,9‐Trithiacyclododecane)European Journal of Inorganic Chemistry, 1996
- Macrocyclic liquid crystalsPhilosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 1996
- Synthesis, structure and reactivity of the thioether half-sandwich rhodium(III) complex [RhCl(MeCN)2([9]aneS3)][CF3SO3]2([9]aneS3= 1,4,7-trithiacyclononane)J. Chem. Soc., Dalton Trans., 1996
- Dinuclear thioether half-sandwich ruthenium(II) complexes of the types [{RuL′([9]aneS3)}2(µ-L)n]2+(n= 1, L′= PPh3; n= 2, L′= MeCN), [{Ru([9]aneS3)}2(µ-L)2]2+and [{Ru([9]aneS3)}2(µ-L)3]+with heterocyclic thioamides L ([9]aneS3= 1,4,7-trithiacyclononane)J. Chem. Soc., Dalton Trans., 1996
- Crown thioether complexes of trivalent transition metal ions. The crystal structure of [Cr(18S6)Cl3]Inorganica Chimica Acta, 1995
- Synthesis and structural characterization of crown thioether complexes of silver(I) and copper(II)J. Chem. Soc., Dalton Trans., 1995
- Spectroscopic studies and X‐ray crystal structures of charge‐transfer complexes of 1,4,7‐trithiacyclononane with diiodineHeteroatom Chemistry, 1993
- The synthesis and low-temperature single crystal X-ray structure of the charge-transfer complex ([9]aneS3)2(l2)4([9]aneS3= 1,4,7-trithiacyclononane)Journal of the Chemical Society, Chemical Communications, 1993
- Chemistry of Thioether Macrocyclic ComplexesAdvances in Inorganic Chemistry, 1990