Abstract
Large anomalous laser‐induced voltages observed in YBa2Cu3Ox are explained as the result of ‘‘off diagonal’’ thermoelectricity, an uncommon phenomenon which may only occur in low symmetry environments. The effect is accompanied by a large electrical impedance transformation and the coupling of electrical and thermal currents in orthogonal directions. It thus offers new thin film applications for power generation, cooling, heat pumping, heat flow measurement, and the fast self‐powered sensing of optical and other radiation energy absorbed in thin layers.