An X-ray photoelectron spectroscopic investigation of the oxidation of manganese
- 1 November 1984
- journal article
- research article
- Published by Taylor & Francis in Philosophical Magazine A
- Vol. 49 (5) , 657-663
- https://doi.org/10.1080/01418618408233293
Abstract
X-ray photoelectron spectroscopy has been used to investigate a range of manganese oxide compounds and the initial stages of oxidation of manganese metal. It is shown that the Mn 2p3/2 binding energy, the extent of multiplet splitting of the 3s level, and the O Is : Mn 2p3/2 signal intensity ratio vary systematically between the different oxides. This information is used to identify oxide species present on the surface of manganese films during oxidation. A reaction sequence Mn→MnO→Mn2O3→MnO2 is demonstrated.Keywords
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