Diastereoselective Ruthenium−Cp Complexation of Enantiopure Arene Compounds Possessing Stereogenic Benzylic Alcohol Functionalities
- 25 October 2001
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 3 (23) , 3667-3670
- https://doi.org/10.1021/ol010197f
Abstract
Enantiopure (arene)ruthenium compounds possessing a stereogenic benzylic alcohol functionality were stereoselectively synthesized by diastereoselective ruthenium−Cp complexation to a distinct arene face. This diastereoselective ruthenium−Cp complexation was further extended to biaryl compounds linked with a six-membered lactone bridge for the synthesis of enantiomerically pure, axially chiral biaryls.Keywords
This publication has 3 references indexed in Scilit:
- Synthesis and Atropo-diastereoselective Ring Cleavage of a [Cp*Ru]-Complexed Biaryl Lactone: Experimental and Computational InvestigationsOrganometallics, 1999
- A Highly Active Catalyst for the Room-Temperature Amination and Suzuki Coupling of Aryl ChloridesAngewandte Chemie International Edition in English, 1999
- Isolierbare KonformationsisomereChemie in Unserer Zeit, 1983