First Heck Reaction with Arenediazonium Cations with Recovery of Pd-Triolefinic Macrocyclic Catalyst
- 2 April 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 5 (9) , 1559-1561
- https://doi.org/10.1021/ol034340b
Abstract
The air- and moisture-stable phosphine-free palladium(0) complex 1 is a highly active and recoverable catalyst for Heck olefination of aryl diazonium tetrafluoroborates. The reactions were performed under aerobic conditions at room temperature to give the coupling products in excellent yields.Keywords
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