Bis[Trinitrato Cerium(IV)] Chromate; [(NO3)3Ce]2CrO4vs Trinitrato Cerium(IV) Chromate Dihydrate; [(NO3)3Ce] CrO4.2H2O in the oxidation of trimethylsilyl ethers
- 1 February 1996
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 26 (4) , 649-655
- https://doi.org/10.1080/00397919608086737
Abstract
Bis[trinitratocerium (IV)] chromate is able to proceed oxidative deprotection of trimethylsilyl ethers in benzene under reflux conditions. Trinitratocerium(IV)chwmate dihydrate is a very sluggish oxidant for this purpose.Keywords
This publication has 20 references indexed in Scilit:
- Zinc Chloride Catalyzed Silylation of Alcohols and Phenols by Hexamethyldisilazane. A Highly Chemoselective ReactionSynthetic Communications, 1993
- Silyl Ethers as Protective Groups for Alcohols: Oxidative Deprotection and Stability under Alcohol Oxidation ConditionsSynthesis, 1993
- Bistriphenylsilanol-Assisted Oxidation Catalyzed by Chromium(VI) Oxide of Activated Trimethylsilyl Ethers with tert -Butyl HydroperoxideSynthetic Communications, 1992
- Bis(triphenylsilyl) Chromate Catalyzed Oxidation of Silyl Ethers bytert-Butyl HydroperoxideSynlett, 1991
- Sequential annulation approach to sterpuric acid and sterpurene-3,12,14-triol, metabolites of the silver leaf fungus Stereum purpureumJournal of the American Chemical Society, 1988
- Diphenylmethylsilyl ether (DPMS): a protecting group for alcoholsThe Journal of Organic Chemistry, 1987
- The reactivity of silyl ethers to the Swern reagentJournal of the Chemical Society, Perkin Transactions 1, 1987
- Use of Organosilicon Reagents as Protective Groups in Organic SynthesisSynthesis, 1985
- Pyridinium Fluorochromate or Benzyltrimethylammonium Chlorochromate for Selective Oxidation of AlcoholsBulletin of the Chemical Society of Japan, 1984
- Direct Conversion of Secondary Trimethylsilyl Ethers to KetonesSynthesis, 1983