Synthesis of Vitamin‐B12 Derivatives with an Electropolymerizable Side Chain
- 1 January 1998
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 81 (5-8) , 1117-1126
- https://doi.org/10.1002/hlca.19980810525
Abstract
Three new derivatives of vitamin B12 with a pyrrole head group attached to the corrin ring have been prepared. Ligand‐exchange reactions and reduction provided reactive CoIII and CoII complexes. Their electro‐chemical properties and their potential for fixation at the surface of electrodes by electropolymerization were studied.Keywords
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