Formation of an Anionic Titanium(IV) Sulfido Dimer, {Na2[CpTi(μ-S)(S)]2·4THF}2, by Elimination of CpH and H2from Cp2Ti(SH)2upon Deprotonation with NaH
- 20 August 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 15 (17) , 3631-3633
- https://doi.org/10.1021/om960358x
Abstract
No abstract availableKeywords
This publication has 35 references indexed in Scilit:
- Synthesis, structure, and reactivity of Lewis acidic cyclopentadienyltitanium dithiolate complexesInorganic Chemistry, 1993
- Addition and cycloaddition reactions of the nucleophilic oxo and sulfido complexes [tmtaa]Ti:X (X = O, S; tmtaa = dianion of 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine)Inorganic Chemistry, 1992
- Disproportionation of sulfur dioxide to octasulfur and sulfur trioxide on Cp*2Cr2S5. Crystallographic and sulfur-34-labeling evidence for an oxygen-transfer mechanism and observation of facile exchange of Cr2S5 core sulfurs with 34S. Structures of Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-.eta.1-SS.cntdot.SO2).cntdot.SO2 and Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-SSO3)Inorganic Chemistry, 1992
- Synthesis of sulfido(pentamethylcyclopentadienyl)tantalum complex (C5Me5)Ta(S)32- and the structure of a hexagonal-prismatic Ta2Li4S6 coreJournal of the American Chemical Society, 1989
- [TiSCl4]2⊖ and [Ti3O(S2)3Cl6]2⊖, a Multinuclear Complex with a Structure Typical for ClustersAngewandte Chemie International Edition in English, 1988
- Oxygenated titanium sulfide clusters. Synthesis and structures of (CH3C5H4)4Ti4S8Ox (x = 1, 2)Inorganic Chemistry, 1986
- Reduction of sulfur dioxide by (C5R5)M(CO)3H (M = Mo, W; R = H, Me). Chemistry and structures of (C5H5)Mo(CO)3(SO2H), the first example of insertion of SO2 into a metal-hydride bond, and [(C5Me5)Mo(CO)3]2(.mu.-S2O4), a sulfur-bonded dithionite complexOrganometallics, 1985
- Homogeneous catalysis of hydrogen reduction of sulfur dioxide to sulfur and water using [(.eta.5-MenCp)Mo(S)(SH)]2Journal of the American Chemical Society, 1985
- Investigation into the reactivity of the metal-metal triple bond in [Cp'(CO)2M]2 (Cp' = .eta.5-C5Me5', M = Mo, W) vs. elemental sulfur. Formation of different Cp'2M2S4 isomers and crystal structures of Cp'2Mo2(.mu.-S2)(.mu.-S)2 and Cp'2(CO)2W2(.mu.-S)2SOrganometallics, 1982
- Syntheses, structures, and reactions of molybdenum complexes with sulfido and disulfido ligandsInorganic Chemistry, 1981