HNMR Chemical Shift Information on the Conformation of the Glycosidic Bond in Disaccharides
- 1 January 1991
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 10 (2) , 159-180
- https://doi.org/10.1080/07328309108543899
Abstract
Experimental 1H NMR chemical shifts were related to results obtained from theoretical calculations, in this case the HSEA approach, in order to obtain information about conformational equilibria about the glycosidic bond of disaccharides. Assuming the existence of the exo-anomeric effect, it was shown that the sign of torsion angle Ψ can be obtained tentatively from the 1H N M R chemical shifts.This publication has 31 references indexed in Scilit:
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