(η5-C5H4SiMe3)3UH: the first stable organouranium(IV) hydride
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 360-361
- https://doi.org/10.1039/c39910000360
Abstract
The synthesis and reactions of (tscp)3UH and [Na(18-crown-6)][(tscp)3UH](tscp =η5-C5H4SiMe3) are described.Keywords
This publication has 11 references indexed in Scilit:
- Reactivity of tricyclopentadienyl uranium tetrahydroaluminateJ. Chem. Soc., Dalton Trans., 1990
- Reactions of cp3UCl (cp =η-C5H5) with various reducing agents: synthesis and crystal structure of the uranium(III) hydride [(cp3U)2(µ-H)][Na(THF)2](THF = tetrahydrofuran)Journal of the Chemical Society, Chemical Communications, 1989
- Derivatives of U(BH4)4 and its Lewis base adducts; synthesis of monocyclopentadienyl- and hydride-uranium(IV) complexes: (η-C5H5)U(BH4)3 and (CH3OCH2CH2OCH3)U(BH4)3HJournal of Organometallic Chemistry, 1988
- Chemistry of trivalent uranium metallocenes: electron-transfer reactions with carbon disulfide. Formation of [(RC5H4)3U]2[.mu.-.eta.1.eta.2-CS2]Inorganic Chemistry, 1986
- Synthesis, properties, and molecular structure of a trivalent organouranium diphosphine hydrideJournal of the American Chemical Society, 1982
- Synthesis and properties of bis(pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compoundsJournal of the American Chemical Society, 1981
- Photochemistry of Transition Metal Hydride ComplexesPublished by Wiley ,1980
- Hydrido[tris(hexamethyldisilylamido)]thorium(IV) and -uranium(IV)Journal of the American Chemical Society, 1979
- Synthesis, chemistry, and spectroscopy of some tris(pentahapto-cyclopentadienyl)uranium(IV) alkyl and aryl compoundsJournal of the American Chemical Society, 1973
- Derivatives of Ferrocene. II. Some Reduction Products of Benzoylferrocene and 1,1'-Dibenzoylferrocene1The Journal of Organic Chemistry, 1957