Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
Open Access
- 29 April 2004
- Vol. 9 (5) , 278-286
- https://doi.org/10.3390/90500278
Abstract
A dinuclear self-assembled cationic macrocycle based on Pt(II)-N(pyridine) coordinative bonds and having competitive triflate anions, as metal counterions, is used in the construction of [2]rotaxane and [2]pseudorotaxane architectures assisted by hydrogen bonding. The kinetic lability of the Pt(II)-N(pyridine) coordinative bond controls the dynamics of the [2]rotaxane.Keywords
This publication has 16 references indexed in Scilit:
- Efficient Modulation of Hydrogen-Bonding Interactions by Remote SubstituentsOrganic Letters, 2003
- Chiroptical Switching in a Bistable Molecular ShuttleJournal of the American Chemical Society, 2003
- A self-assembling polymer-bound rotaxane under thermodynamic controlChemical Communications, 2003
- Highly Sensitive Luminescent Metal-Complex Receptors for Anions through Charge-Assisted Amide Hydrogen BondingInorganic Chemistry, 2003
- Self-Assembly in Palladium(II) and Platinum(II) Chemistry: The Biomimetic ApproachInorganic Chemistry, 2003
- Crosslinking a palladium(ii) polymer gives a laminated sheet structureChemical Communications, 2002
- Thermodynamically self-assembling porphyrin-stoppered rotaxanesNew Journal of Chemistry, 2000
- A New Synthetic Strategy towards Molecules with Mechanical Bonds: Nonionic Template Synthesis of Amide‐Linked Catenanes and RotaxanesAngewandte Chemie International Edition in English, 1997
- Self-Assembly of Cationic, Tetranuclear, Pt(II) and Pd(II) Macrocyclic Squares. x-ray Crystal Structure of [Pt2+(dppp)(4,4'-bipyridyl).cntdot.2-OSO2CF3]4Journal of the American Chemical Society, 1995
- Self‐Assembly of a Dimeric Porphyrin HostAngewandte Chemie International Edition in English, 1994