Photosensing Device Composed of Bilayer Membranes of Polymer-Pendant Ru(bpy)32+and Prussian Blue
- 1 March 1987
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 24 (3-4) , 357-365
- https://doi.org/10.1080/00222338708074453
Abstract
A photosensing device was fabricated based on a photochemical electron transfer reaction. A graphite electrode was coated with bilayer membranes of polymer-pendant Ru(bpy)3 2+ and Prussian Blue (PB) to give a bilayer-coated device. It was irradiated with visible light in an aqueous electrolyte and the induced photocurrent was measured as a function of the applied potential. The excitation of PB was responsible for the anodic photocurrent, while the excitation of the Ru complex mainly induced the cathodic photocurrent by an electron-transfer mechanism.Keywords
This publication has 11 references indexed in Scilit:
- Photoresponsive graphite electrode coated with bilayer membranes of prussian blue and polymer-pendant Ru(bpy)2+3Electrochimica Acta, 1986
- Photoresponsive electrode coated with bilayer membranes of polymer pendant Ru(bpy)2+3 complex and viologenElectrochimica Acta, 1984
- Water Photolysis by Means of Visible Light with a System Composed of Prussian Blue and the Tris(2,2′-bipyridine)ruthenium(II) ComplexBulletin of the Chemical Society of Japan, 1984
- SIMULTANEOUS EVOLUTION OF HYDROGEN AND OXYGEN BY WATER PHOTOLYSIS WITH PRUSSIAN BLUE AND TRIS(2,2′-BIPYRIDYL)RUTHENIUM(II) COMPLEXChemistry Letters, 1982
- Spectroelectrochemistry and electrochemical preparation method of Prussian blue modified electrodesJournal of the American Chemical Society, 1982
- Photoinduced electron transfer from polystyrene pendant tris(2,2′‐bipyridyl)ruthenium (II) complex to methylviologenJournal of Polymer Science: Polymer Chemistry Edition, 1982
- SOLID PHASE PHOTOREDUCTION OF METHYLVIOLOGEN ON CELLULOSE SENSITIZED BY TRIS(2,2′‐BIPYRIDYL)RUTHENIUM COMPLEXPhotochemistry and Photobiology, 1981
- Solid phase photoreduction of methylviologen adsorbed on celluloseNature, 1980
- Electrochemical Oxidation and Reduction of Thin Films of Prussian BlueJournal of the Electrochemical Society, 1978
- The crystal structure of Prussian Blue: Fe4[Fe(CN)6]3.xH2OInorganic Chemistry, 1977