Catalyst-Controlled Diastereoselective Hetero-Diels−Alder Reactions
- 18 April 2002
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 4 (10) , 1795-1798
- https://doi.org/10.1021/ol0258785
Abstract
The diastereoselective hetero-Diels−Alder reaction between Danishefsky's diene and chiral aldehydes is catalyzed by chiral chromium−Schiff base complexes. High levels of catalyst control are obtained in several cases, allowing access to all four stereoisomeric products through appropriate choice of aldehyde and catalyst enantiomers.Keywords
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