Microwave Spectrum and Structure of Sulfuryl Fluoride
- 1 April 1957
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 26 (4) , 734-739
- https://doi.org/10.1063/1.1743394
Abstract
The microwave spectrum of sulfuryl fluoride, SO2F2, has been reinvestigated. The spectra of the S32 and S34 species in natural abundance have been analyzed, and the structure has been determined with the aid of the S34 isotope shift. The correction for zero‐point vibration was shown to be small. The structural parameters are: rSO=1.405±0.003 A, rSF=1.530±0.003 A, 4(A1) and ν5(A2). From an analysis of this interaction the frequency of the hitherto unobserved ν4(A1) fundamental was found to be 388±15 cm—1.Keywords
This publication has 10 references indexed in Scilit:
- Raman Spectra of Thionyl Fluoride and Sulfuryl FluorideThe Journal of Chemical Physics, 1955
- The Microwave Spectrum, Structure, and Dipole Moment of Thionyl Fluoride1Journal of the American Chemical Society, 1954
- The Infrared Spectrum of SO2F2The Journal of Chemical Physics, 1952
- The Microwave Spectrum of a Slightly Aspherical Top—The Structure and Dipole Moment of Sulfuryl FluorideThe Journal of Chemical Physics, 1952
- The Microwave Spectrum of Sulfur DioxideThe Journal of Chemical Physics, 1951
- Molecular Dipole Moments and Stark Effects. II. Stark Effects in OCSPhysical Review B, 1950
- The Stark Effect for a Rigid Asymmetric RotorThe Journal of Chemical Physics, 1948
- The Molecular Structures of Sulfuryl Fluoride and Thiophosphoryl FluorideJournal of the American Chemical Society, 1939
- Two Bands in the Infrared Spectrum of FormaldehydeThe Journal of Chemical Physics, 1937
- The Vibration-Rotation Energy Levels of Polyatomic Molecules II. Perturbations Due to Nearby Vibrational StatesThe Journal of Chemical Physics, 1936