Selective Generation of Organic Aggregates Included within Metal−Organic Micropores through Vapor Adsorption
- 27 January 2005
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 44 (5) , 1421-1424
- https://doi.org/10.1021/ic048351s
Abstract
The ethanol vapor adsorption behavior and the inclusion crystal structure of a 1D-transformable coordination polymer host were characterized. The adsorption jump was observed during phase transition or two-phase equilibrium with abnormal adsorption enthalpy caused by the nature of “mass induced phase transition.” The included ethanol guests selectively form O−H···O hydrogen bonded pairs inside channels, suggesting selective construction of a specific cluster/aggregate in pores under control of thermodynamic factors and cooperative intermolecular interactions among the guest and channel surface.Keywords
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