A Facile Stereoselective Synthesis of Sphingosine and Ceramide
- 1 December 1996
- journal article
- research article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 1996 (12) , 2079-2082
- https://doi.org/10.1002/jlac.199619961219
Abstract
Flexible syntheses of sphingosine and ceramide were achieved by using D‐xylose as the chiral pool and a CuCN‐catalyzed allylic alkylation reaction of a dimesylate 8 for chain elongation with concomitant control of an E configuration of the double bond.Keywords
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