Electronic properties of ionic insulators on semiconductor surfaces: Alkali fluorides on GaAs(100)

Abstract
Photoelectron core-level spectra are measured for the interfaces RbF/GaAs(100) and LiF/GaAs(100). It is found that RbF, of which the lattice almost matches the GaAs lattice, is epi- taxially grown and a F-Ga interface bonding was observed. LiF with a large mismatch to GaAs dissociates after annealing the surface and induces a reconstruction of the GaAs surface. We discuss the present results as compared with our previous investigations of NaF and KF on the same GaAs(100) surface.