Gallium arsenide antimonide: The possibility of lattice-matched LPE growth on InP substrates

Abstract
The possibility of using liquid phase epitaxy (LPE) to grow GaAsxSb1−x on InP substrates has been investigated. Theoretical phase‐diagram calculations for the GaAsSb system show the solidus compositions in the x?0.5 region, where lattice matching to InP occurs, to be strongly dependent on temperature and in some cases multivalued, making it extremely difficult to achieve the degree of temperature control required for deposition of uniform LPE layers. When growths were attempted two‐phase deposits were consistently found, an observation which supports the above conclusions. Appreciable rapid dissolution of the InP substrates was also observed. It is concluded that successful LPE growth of GaAsSb lattice‐matched to InP is unlikely by conventional variable‐temperature LPE techniques.

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