Stereoselective introduction of chiral centres in acylic precursors: a probe into the transition state for V5+-catalyzed t-butylhydroperoxide (TBHP) epoxidation of acyclic allylic alcohols and its synthetic implications.
- 31 December 1982
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 23 (52) , 5579-5582
- https://doi.org/10.1016/s0040-4039(00)85899-2
Abstract
No abstract availableKeywords
This publication has 18 references indexed in Scilit:
- Synthesis of saccharides and related polyhydroxylated natural products. 3. Efficient conversion of 2,3-erythro-aldoses to 2,3-threo-aldosesJournal of the American Chemical Society, 1982
- Vanadium-catalyzed epoxidations. 2. Highly stereoselective epoxidations of acyclic homoallylic alcohols predicted by a detailed transition-state modelJournal of the American Chemical Society, 1981
- Kinetic resolution of racemic allylic alcohols by enantioselective epoxidation. A route to substances of absolute enantiomeric purity?Journal of the American Chemical Society, 1981
- The first practical method for asymmetric epoxidationJournal of the American Chemical Society, 1980
- Chemical synthesis of a proposed enzyme-generated "reactive intermediate analog" derived from thiamin diphosphate. Self-activation of pyruvate dehydrogenase by conversion of the analog to its componentsJournal of the American Chemical Society, 1979
- Stereoselective syntheses of ((E)- and (Z)-1-halo-1-alkenyl)silanes from alkynesThe Journal of Organic Chemistry, 1978
- Synthesis of alkenes from carbonyl compounds and carbanions .alpha. to silicon. 6. Synthesis of terminal allenes and allyl chloridesThe Journal of Organic Chemistry, 1978
- Mechanism of the molybdenum and vanadium catalyzed epoxidation of olefins by alkyl hydroperoxidesThe Journal of Organic Chemistry, 1977
- Kinetics of an associative ligand exchange process: alcohol exchange with arsenate(V) and vanadate(V) estersJournal of the Chemical Society, Chemical Communications, 1976
- New synthesis of aldehydes via vinylsilanesJournal of the American Chemical Society, 1971