Closed-Form Hydrogenic RadialMatrix Elements and the Factorization Method
- 1 August 1973
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 8 (2) , 727-733
- https://doi.org/10.1103/physreva.8.727
Abstract
It is shown that the factorization method, when introducing accelerated ladder operators or accelerated ladder matrices, leads to a formula in closed form for the general off-diagonal () hydrogenic matrix elements. This explicit expression, which involves only factorials and binomial coefficients, is directly reducible to any particular case. The well-known selection rules follow from the formula. The method seems appropriate to other cases of factorizable equations. Its extension to the Dirac-Coulomb, generalized Kepler problems, and the discrete-continuous case is considered.
Keywords
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