Stereoselective Conjugate Reduction of (+)-(7aS)-5,6,7,7a-Tetrahydro-7a-Methyl-1,5-Indandione
- 1 January 1988
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 18 (1) , 115-118
- https://doi.org/10.1080/00397918808057826
Abstract
The title compound has been reduced stereoselectively with DIBAH mediated by t-butylcopper to give trans hydr-1,5-in-dandione (2).Keywords
This publication has 7 references indexed in Scilit:
- Alkylation and silylation of the aluminum enolates generated by hydroalumination of .alpha.,.beta.-unsaturated carbonyl compoundsThe Journal of Organic Chemistry, 1987
- Stereoselective Synthesis of Angularly Methylated Trans Fused Hydrindanone by Conjugate ReductionSynthetic Communications, 1986
- Methylcopper(I)-catalyzed selective conjugate reduction of .alpha.,.beta.-unsaturated carbonyl compounds by di-iso-butylaluminum hydride in the presence of hexamethylphosphoric triamideThe Journal of Organic Chemistry, 1986
- Synthesis of D‐NorgestrelAngewandte Chemie International Edition in English, 1975
- Total syntheses of optically active 19-nor steroids. (+)-Estr-4-ene-3,17-dione and (+)-13.beta.-ethylgon-4-ene-3,17-dioneThe Journal of Organic Chemistry, 1975
- Asymmetric synthesis of bicyclic intermediates of natural product chemistryThe Journal of Organic Chemistry, 1974
- New Type of Asymmetric Cyclization to Optically Active Steroid CD Partial StructuresAngewandte Chemie International Edition in English, 1971