Formation of negative ions in Cs sputter sources

Abstract
A surface ionization model with three-body interaction is used to explain the mass spectra of negative ions from Cs sputter sources as well as their time dependence. The importance of the high diffusion rate from radiation-damaged volumes is illustrated and the difficulties these may cause in quantitative mass spectroscopy with Cs sputter sources are discussed. The anomalously large emittance of single negative ions compared to clusters is ascribed to the surface formation and breakup of negative dimers. An example of negative molecule formation which does not proceed by a surface reaction is given.

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