Synthesis and Characterization of the First Mixed Alkali Metal Enolate Containing Amine Ligands: A Novel “Open‐Stack” Structure and Its Implications for Aldol Addition
- 2 June 1995
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 34 (10) , 1117-1119
- https://doi.org/10.1002/anie.199511171
Abstract
No abstract availableKeywords
This publication has 40 references indexed in Scilit:
- Aggregated intermediates in the aldol reaction sequence. Crystal structure of the open dimer of LiTMP.cntdot.TMEDAJournal of the American Chemical Society, 1993
- Enolates of .alpha.-allenyl ketones: formation and aldol reactions of cumulenolatesJournal of the American Chemical Society, 1992
- Structure of a super base in tetrahydrofuran solution studied by 6Li,1H HOESY, 133Cs,1H HOESY, and MNDO. Evidence for discrete species rather than a mixed aggregateJournal of the American Chemical Society, 1992
- The structure of lithium tetramethylpiperidide and lithium diisopropylamide in the presence of hexamethylphosphoramide: structure-dependent distribution of cyclic and open dimers, ion triplets, and monomersJournal of the American Chemical Society, 1991
- Decamere und dodecamere Natriumamide sowie ein Organonatriumamid mit Stapelstrukturen: [Na10(NMe2)10(tmeda)4], [Na12(NMe2)12(tmeda)4] und [Na12(NMe2)10(CH2C6H4Me)2(tmeda)4]Angewandte Chemie, 1990
- Crystal structure of a unique aggregate containing lithium and potassium cations, ketone enolate, and tert-butoxideJournal of the American Chemical Society, 1989
- Synthesis and crystal structure of the mixed alkali metal imide Li4 -xNa2 +x[NC(Ph)But]6: three (metal–nitrogen)2ring dimers in a triple-layered stackJournal of the Chemical Society, Chemical Communications, 1989
- Thermochemistry of a structurally defined aldol reactionJournal of the American Chemical Society, 1989
- Tetrameres und dodecamerestert-Butylethinyllithium; ein neuartiges Aggregationsprinzip bei OrganolithiumverbindungenAngewandte Chemie, 1987
- Tetrameric and Dodecameric tert‐Butylethynyllithium; A Novel Aggregation Principle in Organolithium CompoundsAngewandte Chemie International Edition in English, 1987