Bimetallic Alkoxides of Zinc and Aluminium
- 1 January 1988
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 18 (1) , 9-19
- https://doi.org/10.1080/00945718808060520
Abstract
Some new bimetallic alkoxides of zinc and aluminium have been synthesised by alcoholysis reactions of [Zn{Al (OPri)4}2; these may be represented by the formulae [Zn{Al (OR4}2] (where R = Me, Et, Prn, Bun, Bui, Bus and Ami) or [Zn{Al (OPri) (OR')3}2] (where R' = But or Amt). With the exception of [Zn{Al (OMe)4}2] and [Zn{Al (OEt)4}2], all the other derivatives are volatile under reduced pressure, soluble in common organic solvents and depict monomeric behaviour in refluxing benzene. Efforts have been made to characterise these new derivatives by a study of their elemental analyses and ir as well as pmr spectra.Keywords
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