Moisture effects on the magnetic state in polyaniline
- 1 November 1991
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 44 (18) , 10393-10395
- https://doi.org/10.1103/physrevb.44.10393
Abstract
Through magnetic-susceptibility measurements on samples of thermally aged polyaniline in the emeraldine-base form, Pauli and Curie susceptibilities are shown to depend sensitively on the presence of moisture. It is suggested that the same spin can contribute either to the Pauli susceptibility or Curie susceptibility depending upon its environment, or temperature, and that the presence of water even in trace amounts may determine the dynamical behavior of the spins.Keywords
This publication has 17 references indexed in Scilit:
- X-ray structure of polyanilineMacromolecules, 1991
- Mizoguchi, Nechtschein, and Travers replyPhysical Review Letters, 1990
- Spin dynamics and conductivity in polyanilinePhysical Review Letters, 1990
- Polyaniline: A material still under discussionSynthetic Metals, 1990
- Spin dynamics in the conducting polymer, polyanilinePhysical Review Letters, 1989
- Multiple lattice phases and polaron-lattice—spinless-defect competition in polyanilinePhysical Review B, 1989
- Cluster Versus Random Doping in Polyaniline: A NMR Approach Based on the 19F- 19F Dipole-Dipole CouplingPublished by Springer Nature ,1989
- Polyaniline: Processability from aqueous solutions and effect of water vapor on conductivitySynthetic Metals, 1987
- Insulator-to-metal transition in polyanilineSolid State Communications, 1987
- Insulator-to-metal transition in polyanilineSynthetic Metals, 1987