Evidence for the technetium(VI) aquanitrido cation [{TcN(OH2)3}2(µ-O)2]2+in solution: preparation and structure of [{TcN(S2CNEt2)}2(µ-O)2]
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1163-1165
- https://doi.org/10.1039/c39900001163
Abstract
Electrophoretic and spectroscopic data together with the isolation and structural characterisation of [{TcN(S2CNEt2)}2(µ-O)2] provide evidence for the formation of the TcVI aquanitrido dimer [{TcN(OH2)3}2(µ-O)2]2+ in solutions of weakly co-ordinating acids.Keywords
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