Accurate Analytical Self-Consistent-Field Wave Functions forAg+

Self-consistent-field calculations by the analytical expansion method were carried out for the ground state of ${\mathrm{Ag}}^{+}\mathrm{}(Z=47\mathrm{})\mathrm{}$, $4d^{10}$, ${}_{}{}^1{}_{}{}^{}S$. All the expansion basis sets were selected so as to satisfy precisely the cusp condition. The deviations from the tail nodal extinction for the radial functions $P_{i\lambda }\mathrm{}\left(r\right)\mathrm{}$ do not exceed 0.000 08. The results represent the most accurate analytical wave functions for ${\mathrm{Ag}}^{+}$ available.