Grazing-incidence x-ray diffraction characterization of Co-Pt magneto-optical thin films

Abstract
The microstructures of epitaxial CoxPt1−x films (x≊0.25 and 0.5) and the orientation relationships with sapphire (0001) single‐crystal substrates were determined by grazing‐incidence x‐ray diffraction. The epitaxial relationships between the CoPt3 film and its substrate are CoPt3[11̄0]∥Al2O3[303̄0] and CoPt3(111)∥Al2O3(0001). A significant amount of the ordered L12 phase was detected in CoPt3. The degree of long‐range order in CoPt3 was 0.3, and the average domain size of the ordered phase was 80 Å. The CoPt film had two domains related by a 30° in‐plane rotation. The epitaxial relationships between the CoPt film and its substrate were CoPt[100]∥Al2O3[303̄0] and CoPt(011)∥Al2O3(0001) for domain A and CoPt[100]∥Al2O3[112̄0] and CoPt(011)∥Al2O3(0001) for domain B. Domain A was found to be dominant and/or had a higher degree of long‐range order than domain B.

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