PALLADIUM(II), PLATINUM(II) AND RHODIUM(III) COMLEXES OF THE DITERTIARY STIBINE, BIS(DIPHENYLSTIBINO)METHANE
- 1 August 1974
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 4 (1) , 47-54
- https://doi.org/10.1080/00958977408075878
Abstract
Eighteen complexes of the ditertiary stibine, bisdiphenylstibinomethane, dsbm, have been isolated and characterized by conductivity and electronic and infrared spectral measurements. Information concerning the structures and of the probable nature of the bonding between the metal and the ligand in the complexes [M(dsbm)X2]2 and M(dsbm)2X2 (M =Pd, Pt; X =Cl, Br, I) and Rh(dsbm)2 X 3 (X =Cl, Br, I) has been obtained from these measurements. Reactions between Ag(I) and Hg(II) salts led to the isolation of the (AgI)2. dsbm and (HgI2)2. dsbm derivatives. The ligand reacts with manganese(III) chloride, iron(III) chloride and copper(II) chloride to form bis(dichlorodiphenylstibino)methane, Ph2 Sb(Cl2)CH2 Sb(Cl2)Ph2.Keywords
This publication has 17 references indexed in Scilit:
- Preparation and properties of bis(diorganostibino)methane substituted metal carbonyl complexesJournal of Organometallic Chemistry, 1972
- Four- and five-coordinate nickel(II) complexes of a bidentate arsenic-antimony ligandInorganic Chemistry, 1971
- The spectrochemical position of antimony(III) ligandsInorganica Chimica Acta, 1971
- Trigonal-bipyramidal nickel(II) complexes of tris(3-dimethylarsinopropyl)stibineInorganica Chimica Acta, 1971
- Anomalous ligand field effects in complexes of quadridentate ligands containing group V donorsInorganica Chimica Acta, 1971
- Tritertiary arsine complexes of tervalent rhodium and iridiumJ. Chem. Soc. A, 1971
- The bis[tris-(o-dimethylarsinophenyl)stibine]nickel(II) cation. A pentaco-ordinate complex containing the novel [Ni(Sb2As3)]2+ donor setJournal of the Chemical Society D: Chemical Communications, 1971
- Study of organoantimony compounds containing the SbCH2Sb moietyJournal of Organometallic Chemistry, 1970
- The vibrational spectra of square planar complexes of formula cis MX2Y2 where M = Pt II or Pd II, X = Cl or Br and Y = Me3P, Me3As or Me3SbSpectrochimica Acta Part A: Molecular Spectroscopy, 1969
- Assignment of the stretching frequencies in some chlorine-bridged platinum(II) complexes, Pt2Cl4L2, with phosphorus and arsenic ligandsSpectrochimica Acta Part A: Molecular Spectroscopy, 1968