Catalytic insertion of diazo compounds into N–H bonds: the copper alternative
- 11 November 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2998-2999
- https://doi.org/10.1039/b207389g
Abstract
The complexes TpXCu (TpX = homoscorpionate) catalyse the insertion of diazo compounds into nitrogen–hydrogen bonds of amines and amides, under very mild conditions, with quantitative yields being obtained with equimolar ratios of reactants.Keywords
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