Entropy-volume correlation for some homovalent disordered solid alloys
- 1 June 1978
- journal article
- Published by IOP Publishing in Journal of Physics F: Metal Physics
- Vol. 8 (6) , 1105-1117
- https://doi.org/10.1088/0305-4608/8/6/013
Abstract
A simple description of the forces in a homovalent disordered alloy allows a prediction of the excess entropy of mixing in terms of the excess volume and the volumes, entropies and Gruneisen parameters of the pure metal components. To within the usually rather large experimental errors, the theory is quite successful. Some implications for more general systems emerge.Keywords
This publication has 9 references indexed in Scilit:
- Excess vibrational entropy and local environment effectsJournal of Physics F: Metal Physics, 1977
- Ab initio calculations of entropies of liquid alloysPhilosophical Magazine, 1977
- Thermodynamic properties of solid alloys: application to MgxCd1-xJournal of Physics F: Metal Physics, 1976
- Pseudopotential Theory of Cohesion and StructurePublished by Elsevier ,1970
- The electrochemical effect in alloys of cadmium, magnesium and mercuryActa Metallurgica, 1969
- Perturbation theory and alloying behaviour I. FormalismJournal of Physics C: Solid State Physics, 1969
- Perturbation theory and alloying behaviour II. The mercury-magnesium systemJournal of Physics C: Solid State Physics, 1969
- Structure of Binary Liquid Mixtures. II. Resistivity of Alloys and the Ion-Ion InteractionPhysical Review B, 1967
- The equilibrium and lattice-spacing relations in the system magnesium-cadmiumProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1940