The Reactions of Sodium Diethyldithiocarbamate and Tetraethylthiuram Disulfide with Mercury(II) Chloride
- 1 October 1976
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 49 (10) , 2780-2783
- https://doi.org/10.1246/bcsj.49.2780
Abstract
Sodium diethyldithiocarbamate (1) and tetraethylthiuram disulfide (2) have been found to react with excess mercury(II) chloride (HgCl2) in water to give complexes with the general formula Et2NCS2HgS2CNEt2·(HgCl2)m−1, where the m value can be as high as five. The complex with m=2 was isolated and characterized. The reaction pathway was discussed in some detail. Also studied were the reactions of 2 with HgCl2 in organic solvents.Keywords
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