Electronic and vibronic Raman scattering from the Mn³⁺ion in Al₂O₃

14 October 1977

journal article
Published by IOP Publishing in Journal of Physics C: Solid State Physics

Vol. 10 (19) , L575-L578
https://doi.org/10.1088/0022-3719/10/19/005

Abstract

Raman scattering transitions have been observed to a number of excited electronic and vibronic states of the ⁵E ground multiplet of Mn³⁺ in Al₂O₃. The positions of these states at zero stress are not in complete agreement with recent calculations. The linear strain-coupling coefficient V_E=3*10⁴ cm^-1 is estimated from the splitting of the state E orbitals under applied uniaxial stress.

Keywords

RAMAN SCATTERING

This publication has 3 references indexed in Scilit:

The Jahn-Teller theory of Mn3+ : Al2O3
Journal de Physique, 1976
Raman scattering from vibronic levels of ${Ni}^{3 +}$ in ${Al}_{2}$ $O_{3}$
Physical Review B, 1975
Far-infrared EPR of ${Al}_{2}$ $O_{3}$ : ${Mn}^{3 +}$ and $γ$ -irradiated ruby
Physical Review B, 1975

Electronic and vibronic Raman scattering from the Mn3+ion in Al2O3

Abstract

Keywords

Electronic and vibronic Raman scattering from the Mn³⁺ion in Al₂O₃