Scaling of Shear-Induced Transformations in Membrane Phases
- 24 September 2002
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 89 (16) , 168301
- https://doi.org/10.1103/physrevlett.89.168301
Abstract
Surfactant sponges are complex-fluid phases made up of convolutions of bilayer sheets. Although isotropic and free flowing they exhibit transient birefringence when stirred, reminiscent of the birefringence of lamellar phases. Previous attempts to understand this effect have led to confusing and often conflicting results. We have used a novel approach to designing the chemical system that gives us control over the relevant parameters needed to study microstructural and macroscopic responses of these phases to shear. We find a remarkable universal scaling behavior for both sponge and shear-induced lamellar states, which resolves a number of long-standing questions about these systems.Keywords
This publication has 25 references indexed in Scilit:
- Influence of Shear on Lyotropic Lamellar Phases with Different Membrane DefectsThe Journal of Physical Chemistry B, 1999
- Shear-Induced Sponge-to-Lamellar Transition in a Hyperswollen Lyotropic SystemPhysical Review Letters, 1996
- Effect of Shear on Dilute Sponge PhaseLangmuir, 1995
- Shear thinning in ternary bicontinuous and water‐in‐oil microemulsionsAIChE Journal, 1995
- Effect of shear on a lyotropic lamellar phaseJournal de Physique II, 1993
- Preparation of monodisperse multilayer vesicles of controlled size and high encapsulation ratio.Journal de Physique II, 1993
- Lamellar phases and disordered phases of fluid bilayer membranesJournal of Physics: Condensed Matter, 1992
- Rheology of ternary microemulsionsThe Journal of Physical Chemistry, 1992
- Viscosity of the L 3 Phase in Amphiphilic SystemsEurophysics Letters, 1990
- Role of shear in the isotropic-to-lamellar transitionPhysical Review Letters, 1989