Differential cross sections for state-selected products by direct imaging: Ar+NO

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Abstract
State‐selected differential cross sections have been obtained by directly imaging the products of collisions in crossed molecular beams. The new technique allows final state resolution and simultaneous detection of all scattering angles. The method has been used to study inelastic collisions between Ar and NO(2Π1/2, υ=0, J=0.5) at a collision energy of 0.21 eV. Rotational rainbows in the product angular distribution are directly observed to change in position as a function of the final rotational state; the peak of the angular distribution moves toward the backward hemisphere and the angular distribution broadens with an increase in final rotational quantum number. The method relies on multiphoton ionization of the product but is otherwise generally applicable to reactive as well as inelastic collisions.