Electronic structure and isomer shifts of Sn halides
- 1 January 1989
- journal article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 39 (1) , 50-56
- https://doi.org/10.1103/physrevb.39.50
Abstract
The all-electron first-principles discrete variational method was employed to study the electronic structure of , , , and . Values of the electronic density at the Sn nucleus were derived and related to isomer shifts to obtain the nuclear constant Δ〈〉. Differences in values of ρ(0) are discussed in terms of the chemical bonding between Sn and halogen atoms.
Keywords
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