Novel Copper-Tartrate Coordination Compounds
- 1 January 1972
- journal article
- other
- Published by Taylor & Francis in Analytical Letters
- Vol. 5 (7) , 497-508
- https://doi.org/10.1080/00032717208064332
Abstract
Using the thermometric enthalpy titration methodology, the hexa-ligand species CuT6 [where T represents the tartrate ion and charges are omitted] has been shown to exist even in dilute tartrate solutions. Kinetic considerations suggest a radical difference between CuT3 CuT2 and the more highly coordinated species CuT3, CuT4, CuT5 and CuT6. It is evident that the hydroxyl groups on the tartrate ion are singularly important contributers to this effectKeywords
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