Aminoborane Polymers as Precursors of C‐N‐B Ceramic Materials
- 1 December 1988
- journal article
- Published by Wiley in Journal of the American Ceramic Society
- Vol. 71 (12) , 1104-1107
- https://doi.org/10.1111/j.1151-2916.1988.tb05799.x
Abstract
Aminoborane polymers were prepared via condensation reactions between polyfunctional amines and either triethylborane or tris(dimethylamino)borane. The products were characterized by chemical and spectroscopic analyses. The thermal degradation of these materials was studied to establish pyrolytic pathways and to evaluate their potential as precursors to C‐N‐B ceramic materials. The borane condensation products with 4,4′‐methylenedipyrazole, o‐phenylenediamine, and 3,3′‐diaminobenzidine produced relatively high ceramic yields at 800°C, whereas that with diethylenetriamine decomposed into partially volatile oligomers.Keywords
This publication has 8 references indexed in Scilit:
- Semiconducting Amorphous Film Containing Carbon Nitrogen and BoronJournal of the Electrochemical Society, 1988
- Precursors to Boron-Nitrogen Macromolecules and CeramicsMRS Proceedings, 1986
- Evaluation of Potential BN Polymer PrecursorsPublished by Wiley ,1985
- Development of ceramics, especially silicon carbide fibres, from organosilicon polymers by heat treatmentPhilosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1980
- Geminal poly(1-pyrazolyl)alkanes and their coordination chemistryJournal of the American Chemical Society, 1970
- The effects of explosions on materialsJournal of Structural Chemistry, 1965
- Boron-Nitrogen Compounds. VIII.1,2 2-Dimethylamino-1,3,2-benzodiazaborolineThe Journal of Organic Chemistry, 1962
- PolybenzborimidazolinesJournal of Polymer Science, 1962