Ion rotational distributions for near-threshold photoionization of H2O
- 15 May 1992
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 96 (10) , 7848-7851
- https://doi.org/10.1063/1.462381
Abstract
Ion rotational distributions for single‐photon VUV photoionization of the 1b1 orbital of the X̃ 1A1 ground state of the jet‐cooled water are reported. These spectra reveal significant type a transitions which are seen to arise from odd angular momentum components of the photoelectron matrix element. The resulting photoionization dynamics are quite nonatomic‐like.Keywords
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