N.M.R. investigations and the molecular field theory of nematic mixtures
- 1 June 1989
- journal article
- research article
- Published by Taylor & Francis in Liquid Crystals
- Vol. 4 (6) , 625-635
- https://doi.org/10.1080/02678298908033197
Abstract
N.M.R. measurements have shown that the mixture E5 can be described by a single order parameter. Based on molecular field theory the nematic-isotropic transition and the temperature dependence of the order parameter in the nematic phase are considered for a binary mixture of nematogens. Guided by the results of the N.M.R. measurements the binary mixture is treated as an effective medium characterized by a single order parameter. Soft attractive forces are taken into account as well as the excluded volume. The coexistence of nematic and isotropic phases in the phase transition region is discussed in detail.Keywords
This publication has 13 references indexed in Scilit:
- Transition temperatures of binary nematic mixtures predicted by the Humphries-James-Luckhurst theoryJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1988
- Pretransitional behaviour in nematogenic mixtures A molecular field theoryLiquid Crystals, 1987
- Nematic and Smectic Ordering of 4-n-Octyl-4′-cyanobiphenyl Studied by Carbon- 13 NMRMolecular Crystals and Liquid Crystals, 1986
- Nematic ordering of 4-n-alkyl-4′-cyanobiphenyls studied by carbon-13 NMR with off-magic-angle spinningThe Journal of Chemical Physics, 1986
- Computer simulation studies of anisotropic systems XIV. Binary mixtures of liquid crystalsLiquid Crystals, 1986
- Behaviour of Aklyloxybenzylidenealkylanilines in the Smectic G PhaseMolecular Crystals and Liquid Crystals, 1985
- A Molecular Field Treatment of Nematic Liquid Crystalline Mixtures: Effects of the Intermolecular Requlsions on Nematic-Isotropic Phase Transition in Binary MixturesJournal of the Physics Society Japan, 1983
- Van der Waals theory of nematogenic solutions. I. Derivation of the general equationsPhysical Review A, 1978
- A statistical theory of liquid crystalline mixtures. Components of different sizeChemical Physics Letters, 1973
- A molecular field treatment of liquid crystalline mixturesSymposia of the Faraday Society, 1971