Enantioselective CO2 Fixation Catalyzed by Optically Active Cobalt Complexes
- 10 May 2004
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 33 (6) , 676-677
- https://doi.org/10.1246/cl.2004.676
Abstract
In the presence of a catalytic amount of optically active cobalt complexes and amine bases, a racemic epoxide, such as N,N-diphenylaminomethyloxirane, reacted with gaseous carbon dioxide to afford the optically active cyclic carbonate along with the optically active starting epoxide.Keywords
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