Mode of formation of polymeric [{Ru(bipy)(CO)2}n](bipy = 2,2′-bipyridine) films
- 1 January 1996
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 2581-2583
- https://doi.org/10.1039/dt9960002581
Abstract
Electrochemical generation of the organometallic polymer [{Ru0(bipy)(CO)2}n] by reduction of [RuII(trans-Cl2)(bipy)(CO)2] proceeded via the formation of the corresponding dimer [{RuI(trans-Cl)(bipy)(CO)2}2] and a tetrameric species; only dimers were formed by electroreduction of the [RuII(cis-Cl2)(bipy)(CO)2] isomer or [RuIICl(bipy){cis-(CO)2}(CO2Me)].Keywords
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