Efficient cleavage of adenylyl(3′-5′)adenosine by triethylenetetraminecobalt(III)
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1050-1051
- https://doi.org/10.1039/c39900001050
Abstract
Cleavage of adenylyl(3′-5′)adenosine is 105 fold accelerated by [Co(triethylenetetramine)(H2O)2]3+(0.2 M) at pD 6, 50 °C.Keywords
This publication has 11 references indexed in Scilit:
- On the mechanism of catalysis by ribonuclease: cleavage and isomerization of the dinucleotide UpU catalyzed by imidazole buffersJournal of the American Chemical Society, 1989
- On the mechanism of action of ribonucleases: dinucleotide cleavage catalyzed by imidazole and Zn2+.Proceedings of the National Academy of Sciences, 1989
- Cobalt(III) complex-promoted hydrolysis of phosphate diesters: comparison in reactivity of rigid cis-diaquo(tetraaza)cobalt(III) complexesJournal of the American Chemical Society, 1989
- Cobalt(III) complex promoted hydrolysis of phosphate diesters: change in rate-determining step with change in phosphate diester reactivityJournal of the American Chemical Society, 1988
- Metal-activated hydrolytic cleavage of DNAJournal of the American Chemical Society, 1987
- Catalytic hydrolysis of cAMPCanadian Journal of Chemistry, 1987
- Metals and DNA: Molecular Left-Handed ComplementsScience, 1986
- Design of Sequence-Specific DNA-Binding MoleculesScience, 1986
- Hydrolysis of nucleoside phosphates. 9. Comparison of the effectiveness of various metal ions on the promoted dephosphorylation of adenosine 5'-triphosphate (ATP) and uridine 5'-triphosphate (UTP)Journal of the American Chemical Society, 1985
- Hydrolysis of phosphate esters bound to cobalt(III). Kinetics and mechanism of intramolecular attack of hydroxide on coordinated 4-nitrophenyl phosphateJournal of the American Chemical Society, 1983