Photodissociation cross sections from the E,F state of H2

15 December 1986

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 85 (12) , 7180-7183
https://doi.org/10.1063/1.451352

Abstract

Photodissociation cross sections were calculated for transitions from the v=6, J=1 level of the E,F ¹∑⁺_g state of H₂ to the continua of the B ¹∑⁺_u, C ¹∏_u, and B’ ¹∑⁺_u states. The results include the first accurate calculations of transitions to the continua of these states for energies extremely close to threshold. The need for a small adjustment to the B’ state potential was established, and a simple ad hoc procedure for this was developed. The calculations predict a prominent resonance very near threshold, and oscillatory behavior at larger energies.

Keywords

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