Luminescent Organogold(III) Complexes with Long‐Lived Triplet Excited States for Light‐Induced Oxidative C-H Bond Functionalization and Hydrogen Production
- 3 February 2012
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 51 (11) , 2654-2657
- https://doi.org/10.1002/anie.201108080
Abstract
All that glitters is gold: Highly phosphorescent gold(III) complexes (see picture) with extended π‐conjugated cyclometalating ligands exhibit rich photophysical and photochemical properties. They act as efficient photocatalysts/photosensitizers for oxidative functionalizations of secondary and tertiary benzylic amines and homogeneous hydrogen production from a water/acetonitrile mixture.Keywords
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