Photoinduced Ru–Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4]2−and Yb(iii) units
- 21 April 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- No. 10,p. 1524-1526
- https://doi.org/10.1039/b404820b
Abstract
Co-crystallisation of the anionic cyanometallate chromophore [Ru(bipy)(CN)4]2− with Yb(III) provides coordination polymers or oligomers containing Ru–CN–Yb bridges; in [K(H2O)4][Yb(H2O)6][Ru(bipy)(CN)4]2·5H2O Ru → Yb energy-transfer (k > 5 × 106 s−1) results in partial quenching of the Ru-based luminescence and sensitised near-IR luminescence from the Yb(III) unit.Keywords
This publication has 27 references indexed in Scilit:
- Sensitized Near‐Infrared Emission from Complexes of YbIII, NdIII and ErIII by Energy‐Transfer from Covalently Attached PtII‐Based Antenna UnitsChemistry – A European Journal, 2003
- Charge transfer fluorescence and f–f luminescence in ytterbium compoundsOptical Materials, 2003
- Lanthanide−Transition-Metal Complexes: From Ion Pairs to Extended ArraysAccounts of Chemical Research, 2003
- The crystal structure of [Sm(H2O)5][Ru2(bpy)2(CN)7]·11H2O, a novel mixed d–f coordination polymerCrystEngComm, 2003
- Singlet Energy Transfer as the Main Pathway in the Sensitization of Near-Infrared Nd3+ Luminescence by Dansyl and Lissamine DyesChemphyschem, 2002
- Solvatochromism as a mechanism for controlling intercomponent photoinduced processes in a bichromophoric complex containing [Ru(bpy)3]2+ and [Ru(bpy)(CN)4]2– unitsJ. Chem. Soc., Dalton Trans., 2002
- Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two-Dimensional Topological Architecture and Unusual Magnetic BehaviorAngewandte Chemie International Edition in English, 2001
- Tunable Energy Transfer from Dicyanoaurate(I) and Dicyanoargentate(I) Donor Ions to Terbium(III) Acceptor Ions in Pure CrystalsInorganic Chemistry, 2000
- Porphyrin sensitization of circularly polarised near-IR lanthanide luminescence: enhanced emission with nucleic acid bindingChemical Communications, 2000
- Photophysics of Supercomplexes. Adduct between Ru(bpy)(CN)42- and the [32]ane-N8H88+ Polyaza MacrocycleInorganic Chemistry, 1996