The crystal structure of [Sm(H2O)5][Ru2(bpy)2(CN)7]·11H2O, a novel mixed d–f coordination polymer
- 1 January 2003
- journal article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 5 (88) , 495-497
- https://doi.org/10.1039/b313122j
Abstract
This communication describes the crystal structure of the mixed-metal coordination polymer {[Sm(H2O)5][Ru(CN)3(bpy)-(μ-CN)-Ru(CN)3(bpy)]·11H2O}∞, which was isolated in low yield from co-crystallisation of K2[Ru(bpy)(CN)4] with Sm(NO3)3·6H2O. This polymeric chain extends along the a-axis and is constructed from cyanide ligands bridging Ru and Sm metal vertices; it contains both hydrophobic and hydrophilic channels, the latter filled with an H-bonded network of water molecules.Keywords
This publication has 22 references indexed in Scilit:
- Sensitized Near‐Infrared Emission from Complexes of YbIII, NdIII and ErIII by Energy‐Transfer from Covalently Attached PtII‐Based Antenna UnitsChemistry – A European Journal, 2003
- Sensitised near-infrared emission from lanthanides using a covalently-attached Pt(ii) fragment as an antenna groupElectronic supplementary information (ESI) available: characterisation data and luminescence spectra. See http://www.rsc.org/suppdata/cc/b3/b301878d/Chemical Communications, 2003
- Lanthanide−Transition-Metal Complexes: From Ion Pairs to Extended ArraysAccounts of Chemical Research, 2003
- A simple, general synthesis of mixed d–f complexes containing both {Re(CO)3Cl(diimine)} and lanthanide-tris(β-diketonate) luminophores linked by bis-diimine bridging ligandsJ. Chem. Soc., Dalton Trans., 2002
- Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two-Dimensional Topological Architecture and Unusual Magnetic BehaviorAngewandte Chemie International Edition in English, 2001
- Direct Evidence for O−H···NC Hydrogen Bonding in a Cyanide-Bridged Lanthanide−Transition-Metal Complex (H2O)6(DMF)6Ho2[Ni(CN)4]3: An Eight-Coordinated Holmium Center with a Bicapped (Square Face) Trigonal Prismatic GeometryInorganic Chemistry, 2000
- Tunable Energy Transfer from Dicyanoaurate(I) and Dicyanoargentate(I) Donor Ions to Terbium(III) Acceptor Ions in Pure CrystalsInorganic Chemistry, 2000
- Influence of Solvent on the Spectroscopic Properties of Cyano Complexes of Ruthenium(II)The Journal of Physical Chemistry, 1996
- Volume changes associated with intramolecular electron transfer during MLCT state formation. Time‐resolved optoacoustic studies of ruthenium cyano complexesRecueil des Travaux Chimiques des Pays-Bas, 1995
- Photoluminescence studies of lanthanide ion complexes of gold and silver dicyanides. 2. A new low dimensional solid state class for nonradiative excited state energy transferInorganic Chemistry, 1994