The P V T properties of nitrogen from −20 to +35 °C and 200 to 570 MPa, and some comparisons with argon and the Lennard-Jones (6-12) fluid
- 15 September 1983
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 79 (6) , 2982-2988
- https://doi.org/10.1063/1.446127
Abstract
The density ρ(T, p) of nitrogen has been measured for T=−20 to +35 °C and p in the range 200 to 570 MPa, using a method already described in a paper which included results for argon. An improvement in the accuracy with which the quantities of gas are measured has reduced the overall uncertainty in ρ(T, p) to 0.03% at the 95% confidence level. The results are presented graphically and in the form of a fitted equation, and are compared with those of other workers. A comparison is made with the results of the argon study and a hypothetical Lennard‐Jones fluid, in terms of the density, the internal energy and the entropy, and the internal kinetic energy of the molecules as calculated by Schottky’s method.Keywords
This publication has 12 references indexed in Scilit:
- Isotherms of argon between 0°c and 150°c and pressures up to 2900 atmospheresPublished by Elsevier ,2004
- Accurate method for high pressure PVT measurements and results for argon for T=−20 to +35 °C and p in the range 200–480 MPaThe Journal of Chemical Physics, 1980
- Equation of state for the Lennard-Jones fluidMolecular Physics, 1979
- Sound velocity and the equation of state of N2 to 22 kbarThe Journal of Chemical Physics, 1975
- Thermodynamic Properties of Nitrogen Including Liquid and Vapor Phases from 63 K to 2000 K with Pressures to 10,000 BarJournal of Physical and Chemical Reference Data, 1973
- Isotherms of Nitrogen to 400°C and 10 000 barThe Journal of Chemical Physics, 1969
- Pressure derivatives of the elastic constants of α-iron to 10 kbsJournal of Physics and Chemistry of Solids, 1968
- Thermodynamical properties of argon as function of pressure and temperature between 0 and 2000 atmospheres and 0° and 150°CApplied Scientific Research, 1951
- Pressure, Volume, Temperature Properties of Nitrogen at High Density. II. Results Obtained by a Piston Displacement MethodJournal of the American Chemical Society, 1937
- Isotherms of nitrogen between 200 and 3000 atm. and 0° and 150°Physica, 1936