Energy flow pathways and their spectral signatures in vibrationally excited acetylene
- 1 September 1988
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 89 (5) , 3379-3381
- https://doi.org/10.1063/1.454948
Abstract
Algebraic methods and classical trajectory studies for a model Hamiltonian which includes all in-plane vibrational modes are used to elucidate the origin of spectral structure in the stimulated emission spectra of acetylene. The molecular oscillators responsible for previously established gateway states are determined as well as a plausible description of the overall IVR mechanism.Keywords
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